Design and synthesis of a high potential ruthenium (II) tetraazatetrapyridopentaphene complex capable of two-electron reduction
We report the synthesis of a complex, [(phen)2Ru(tatpph)Ru(phen)2]4 (Ph4), which like its predecessor compound, [(phen)2Ru(tatppc)Ru(phen)2]4 (Pc 4+), can undergo two sequential 1-electron photoreductions in MeCN in the presence of a sacrificial reductant. The initial complex, Ph 4+, can be complete...
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| Format: | Electronic Resource |
| Language: | English |
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Ann Arbor Michigan
ProQuest LLC
[2010]
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| Online Access: | Full text access requires UP Webmail login |